Cuba Libre
Season 1, Episode 8, “The Grasshopper Experiment” (2008) · Sheldon Cooper (served by Penny)
Practising for a bartending shift, Penny makes the guys order cocktails; Sheldon asks for a virgin (diet) Cuba Libre, and later at the bar Penny secretly adds rum, which gets him singing.
“Fine, I'll have a virgin Cuba Libre.”
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Sources: Wikiquote - The Big Bang Theory (season 1), 'The Grasshopper Experiment'; Miss Charming (Cheryl Charming) - Cocktails in Television